Dr.
Sametz's CHE 322 Page
Spring 2012
Syllabus
Office Hours: W F, 10-11
a.m., 169 BRL
Recitation: MTW 12:30-2:30,
208 LDL
Laboratory Material
Laboratory Schedule
Lab Notebook/Report Format
and Example
Steam Distillation of Clove Oil
Aldehydes and Ketones
Grignard
Vanillin Reduction
Wittig
Identification of an Unknown
Spectra for labs:
aldehydes and ketones
salicylic acid acetylsalicylic acid
isopentyl acetate NMR and IR
unknowns lab (.zip)
Reading (sections of textbook
chapters)
11: 11.3,11.4, 11.7, 11.8.
12: 12.1, 12.2, 12.4-12.6,12.9-12.12.
13: 13.1-13.9,13.11 (part a only; no Birch reduction), 13.12.
14: 14.1, 14.2, 14.4-14.7, 14.9-14.11.
15: 15.5-15.8. 15.4 (IR spectroscopy) is "extra credit".
16: 16.1-16.15, 16.17
17: 17.1-17.7 (omit 17.7c, Kolbe electrolysis in g, h)
18: 18.1-18.10 (omit reductions and cuprate addition on p. 892-3)
19: 19.1-19.9, 19.11, 19.15 (omit 19.4b and cuprate additions on
p. 980)
22: 22.1, 22.2, 22.4a-c, 22.6
23: 23.1, 23.2a-d
Homework
Chapter 11: 41abce, 45, 47-49.
Chapter 12: 38, 39, 42-44, 46, 48, 49, 51, 52, 57, 60-63.
Chapter 13: 28, 29, 31, 33, 34, 37, 38, 41, 43-48, 51, 52, 54, 56,
60.
Chapter 14: 45-50, 54, 55, 57, 60, 61.
Chapter 15: 32, 33, 35, 48, 50-54, 57-58, 64-66, 71-83
Chapter 16: 31-37, 39-50, 52, 57, 59-60, 62, 63, 65, 67
Chapter 17: 25-33, 35, 36a-c, 38-39, 43-45, 48, 49bd
Chapter 18: 33-39, 42 (A-->E), 45a-d, 49, 50.
Chapter 19: 47-64, 67-73, 77.
Chapter 22: 26a, b, d, 27, 42, 44.
Exam Keys:
E1
E2
E3
Old Exams
2009:
E1
E2
E3 Final
2010: TTh E1 E2
E3
MWF E1 E2 E3
Final
Additional Materials:
Ch. 14: Directing groups in
EAS reactions.
Ch. 15: Spectroscopy powerpoint slides: .pptx .ppt .pdf (.pdf is
inferior quality b/c of animations)
Ch. 17: Kinetic vs. Thermodynamic Enolates
Food chemistry slides
Biochemistry slides
Links
Prof.
Koh's 322 website. Includes past exams, spectroscopy
problems and other materials.
Electron-pushing
guide from Prof. Hans Reich at the University of
Wisconsin. He also has links to other guides at the bottom of
his page.
WebSpectra.
A
collection of spectroscopy problems for practice.
The
University of Colorado at Boulder has another collection of
spectroscopy problems.
More
spectroscopy problems at Michigan State University.
There are several short-answer, exam-worthy questions via the
pulldown menu at the bottom of the page.
Online
organic chemistry text at Michigan State University.
Organic
Chemistry As a Second Language by D. R. Klein (link goes to
Amazon.com). I've only flipped briefly through these two
books, butthey look appropriate, and I've heard many students find
them helpful. If you're looking for additional study
resources, check them out and see if they're worth the money to you.
If you find online resources that you like, and think other students
would find useful, let me know!