| Surface Spectroscopies/Microscopies |
| *Kelly S.D., Hesterberg D., Ravel B. 2008. Analysis of Soils and Minerals Using X-ray Absorption Spectroscopy, in: A. L. Ulery and L. R. Drees (Eds.), Methods of Soil Analysis. Part 5. Mineralogical Methods, Soil Science Society of America, Madison, WI. |
| *Landrot, G., M. Ginder-Vogel and D.L. Sparks. 2010. Kinetics of chromium(III) oxidation by manganese(IV) oxides using Quick Scanning X-ray Absorption Fine Structure Spectroscopy (Q-XAFS). Environ. Sci. Technol. 44 (1): 143–149.
|
| O'Day P.A. 1999. Molecular environmental geochemistry. Reviews of Geophysics 37:249-274. |
| Paul K.W., Borda M.J., Kubicki J.D., Sparks D.L. 2005. Effect of dehydration on sulfate coordination and speciation at the Fe-(Hydr)oxide-water interface: A molecular orbital/density functional theory and Fourier transform infrared spectroscopic investigation. Langmuir 21:11071-11078. |
| Paul, K.W., J.D. Kubicki and D. L. Sparks. 2006. Quantum chemical calculations of sulfate adsorption at the Al- and Fe-(Hydr)oxide-H2O interface-Estimation of Gibbs free energies. Environ. Sci. Technol. 40:7717 -7724. |
| Paul, K.W., J.D. Kubicki and D. L. Sparks. 2007. Sulphate adsorption at the Fe (hydr)oxide–H2O interface: comparison of cluster and periodic slab DFT predictions, European J Soil Sci. 58:978-988. |
| *Sutton S.R. 2006. User research facilities in the earth sciences. Elements 2:7-8. |
| Sutton S.R., Caffee M.W., Dove M.T. 2006. Synchrotron radiation, neutron, and mass spectrometry techniques at user facilities. Elements 2:15-21. |
| Toor, G.S., S. Hunger, J.D. Peak, J.T. Sims and D.L. Sparks. 2006. Advances in the Characterization of Phosphorus in Organic Wastes: Environmental and Agronomic Applications, In Advances in Agronomy, 89:1-72. |
Sorption |
| Abu A., Smith S. 2006. Mechanistic characterization of adsorption and slow desorption of phenanthrene aged in soils. Environ. Sci. Technol. 40:5409-5414. |
| Alexandratos V.G., Elzinga E.J., Reeder R.J. 2007. Arsenate uptake by calcite: Macroscopic and spectroscopic characterization of adsorption and incorporation mechanisms. Geochim. Cosmochim. Acta 71:4172-4187. |
Arai, Y. and D. L. Sparks. 2001. ATR-FTIR spectroscopic investigation on phosphate adsorption mechanisms at the ferrihydrite-water interface. J. Colloid Interf. Sci. 241: 317-326. |
Arai, Y. , E. J. Elzinga, and D. L. Sparks. 2001. X-ray absorption spectroscopic investigation of arsenite and arsenate adsorption at the aluminum oxide-water interface. J. Colloid Interf. Sci. 235:80-88. |
| Arai, Y., D.L. Sparks, and J.A. Davis. 2004. Effects of dissolved carbonate on arsenate adsorption and surface speciation at the hematite-water interface. Environ. Sci. Technol. 38:817-824. |
| Arai, Y., D. L. Sparks and J. A. Davis 2005. Arsenate adsorption mechanisms at the allophane-water interface. Environ. Sci. Technol. 39:2537 - 2544. |
| Arai Y., McBeath M., Bargar J.R., Joye J., Davis J.A. 2006. Uranyl adsorption and surface speciation at the imogolite-water interface: Self-consistent spectroscopic and surface complexation models. Geochim. Cosmochim. Acta 70:2492-2509. |
| Arai Y., Moran P.B., Honeyman B.D., Davis J.A. 2007. In situ spectroscopic evidence for neptunium(V)-carbonate inner-sphere and outer-sphere ternary surface complexes on hematite surfaces. Environ. Sci. Technol. 41:3940-3944. |
| Arai Y. 2008. Spectroscopic evidence for Ni(II) surface speciation at the iron oxyhydroxides - Water interface. Environ. Sci. Technol. 42:1151-1156. |
| Arai Y. 2010. X-ray absorption spectroscopic investigation of molybdenum multinuclear sorption mechanism at the goethite/water interface. Environmental Science & Technology 44:8491-8496. |
| Arai Y. 2010. Effects of dissolved calcium on arsenate sorption at the kaolinite-water interface. Soil Science 175:207-213. |
| Axe L., Bunker G.B., Anderson P.R., Tyson T.A. 1998. An XAFS analysis of strontium at the hydrous ferric oxide surface. J. Colloid Interface Sci. 199:44-52. |
Bargar, J. R., S. N. Towle, G. E. Brown, Jr. and G. A. Parks. 1997. XAFS and bond-valence determination of the structures and compositions of surface functional groups and Pb(II) and Co(II) sorption products on single-crystal γ-Al2O3. J. Colloid Interface Sci. 185:473-492. |
| Beak D.G., Basta N.T., Scheckel K.G., Traina S.J. 2008. Linking solid phase speciation of Pb sequestered to birnessite to oral Pb bioaccessibility: Implications for soil remediation. Environ. Sci. Technol. 42:779-785. |
| Bochatay L., Persson P., Sjoberg S. 2000. Metal ion coordination at the water-manganite (σ-MnOOH) interface I. An EXAFS study of cadmium(II). J. Colloid Interface Sci. 229:584-592. |
| Boyle-Wight E.J., Katz L.E., Hayes K.F. 2002. Macroscopic studies of the effects of selenate and selenite on cobalt sorption to γ-Al2O3. Environ. Sci. Technol. 36:1212-1218. |
| Boyle-Wight E.J., Katz L.E., Hayes K.F. 2002. Spectroscopic studies of the effects of selenate and selenite on cobalt sorption to γ-Al2O3. Environ. Sci. Technol. 36:1219-1225. |
| Bronner G., Goss K.-U. 2010. Sorption of organic chemicals to soil organic matter: Influence of soil variability and pH dependence. Environmental Science & Technology 45:1307-1312. |
| Brown G.E., Jr., Foster A.L., Ostergren J.D. 1999. Mineral surfaces and bioavailability of heavy metals: A molecular-scale perspective. PNAS 96:3388-3395. |
| Buschmann J., Kappeler A., Lindauer U., Kistler D., Berg M., Sigg L. 2006. Arsenite and arsenate binding to dissolved humic acids: Influence of pH, type of humic acid, and aluminum. Environ. Sci. Technol. 40:6015-6020. |
| Catalano J.G., Zhang Z., Park C.Y., Fenter P., Bedzyk M.J. 2007. Bridging arsenate surface complexes on the hematite (012) surface. Geochim. Cosmochim. Acta 71:1883-1897. |
| *Catalano J.G., Park C., Fenter P., Zhang Z. 2008. Simultaneous inner- and outer-sphere arsenate adsorption on corundum and hematite. Geochim. Cosmochim. Acta 72:1986-2004. |
| Catalano J.G., Luo Y., Otemuyiwa B. 2011. Effect of aqueous Fe(II) on arsenate sorption on goethite and hematite. Environmental Science & Technology 45:8826-8833. |
| Charlet L., Manceau A. 1992. X-ray absorption spectroscopic study of the sorption of Cr(III) at the oxide-water interface. II: Adsorption, coprecipitation and surface precipitation on ferric hydrous oxides. J. Colloid Interface Sci. 148:443-458. |
| Chen C.C., Coleman M.L., Katz L.E. 2006. Bridging the gap between macroscopic and spectroscopic studies of metal ion sorption at the oxide/water interface: Sr(II), Co(II), and Pb(II) sorption to quartz. Environ. Sci. Technol. 40:142-148. |
| Choi S., O'Day P.A., Rivera N.A., Mueller K.T., Vairavamurthy M.A., Seraphin S., Chorover J. 2006. Strontium speciation during reaction of kaolinite with simulated tank-waste leachate: Bulk and microfocused EXAFS analysis. Environ. Sci. Technol. 40:2608-2614. |
| *Chorover J., Kretzschmar R., Garcia-Pichel F., Sparks D.L. 2007. Soil biogeochemical processes within the Critical Zone. Elements 3:321-326. |
| *Christl I., Kretzschmar R. 2007. C-1s NEXAFS spectroscopy reveals chemical fractionation of humic acid by cation-induced coagulation. Environ. Sci. Technol. 41:1915-1920. |
| Dowding, C.E., M.J. Borda, M.V. Fey and D. L. Sparks. 2005. A new method for gaining insight into the chemistry of drying mineral surfaces using ATR-FTIR. J. Colloid Interf. Sci. 292:148-151. |
| Dyer, J. A., P. Trivedi, N. C. Scrivner and D. L. Sparks. 2003. Lead sorption onto ferrihydrite. 2. Surface complexation modeling. Environ. Sci. Technol.37: 915-922. |
| Dyer, J. A., P. Trivedi, N. C. Scrivner and D. L. Sparks. 2004. Surface complexation modeling of zinc sorption onto ferrihydrite. J. Colloid Interf. Sci. 270:55-65. |
| Elzinga, E.J., and D.L. Sparks. 1999. Nickel sorption mechanisms in a pyrophyllite-montmorillonite mixture. J. Colloid Interf. Sci. 213:506-512. |
Elzinga, E. J., D. Peak and D. L. Sparks. 2001. Spectroscopic studies of Pb(II)-sulfate interactions at the goethite-water interface . Geochim. Cosmochim. Acta 65:2219-2230. |
Elzinga, E. J. and D. L. Sparks. 2001. Reaction condition effects on nickel sorption mechanisms in illite-water suspensions. Soil Sci. Soc. Am. J. 65:94-101. |
| Elzinga, E. J. and D. L. Sparks. 2002. X-ray absorption spectroscopy study of the effects of pH and ionic strength on Pb(II) sorption to amorphous silica . Environ. Sci. Technol. 36: 4352 -4357. |
| Fendorf, S.E., G.M. Lamble, M.G. Stapleton, M.J. Kelley, and D.L. Sparks. 1994. Mechanisms of chromium(III) sorption on silica: I. Cr(III) surface structure derived by extended x-ray absorption fine structure (EXAFS) spectroscopy. Environ. Sci. Technol. 28:284-289. |
*Fendorf, S., M. J. Eick, P. Grossl and D. L. Sparks. 1997. Arsenate and chromate retention mechanisms on goethite. I. Surface structure. Environ. Sci. Technol. 31:315-320. |
Fitts, J. P., G. E. Brown, Jr., and G. A. Parks. 2000. Structural evolution of Cr(III) polymeric species at the γ-Al2O3 water interface. Environ. Sci. Technol. 34:5122-5128. |
| Fox P.M., Davis J.A., Zachara J.M. 2006. The effect of calcium on aqueous uranium(VI) speciation and adsorption to ferrihydrite and quartz. Geochim. Cosmochim. Acta 70:1379-1387. |
| Fukushi K., Sverjensky D.A. 2007. A predictive model (ETLM) for arsenate adsorption and surface speciation on oxides consistent with spectroscopic and theoretical molecular evidence. Geochim. Cosmochim. Acta 71:3717-3745. |
| Gräfe, M., R.V. Tappero, M. A. Marcus, and D. L. Sparks. 2008. Arsenic speciation in multiple metal environments: I. Bulk-XAFS spectroscopy of model and mixed compounds. J. Colloid Interface Sci. 320:383-399. |
| Guine V., Spadini L., Sarret G., Muris M., Delolme C., Gaudet J.P., Martins J.M.F. 2006. Zinc sorption to three gram-negative bacteria: Combined titration, modeling, and EXAFS study. Environ. Sci. Technol. 40:1806-1813. |
| Hale S., Hanley K., Lehmann J., Zimmerman A., Cornelissen G. 2011. Effects of chemical, biological, and physical aging as well as soil addition on the sorption of pyrene to activated carbon and biochar. Environmental Science & Technology 45:10445-10453. |
| He Z.L., Zhang M., Yang X.E., Stoffella P.J. 2006. Release behavior of copper and zinc from sandy soils. Soil Sci. Soc. Am. J 70:1699-1707. |
Hug, S. J. 1997. In situ Fourier transform infrared measurements of sulfate adsorption on hematite in aqueous solutions. J. Colloid Interface Sci. 188:415-422. |
| Jia Y.F., Xu L.Y., Wang X., Demopoulos G.P. 2007. Infrared spectroscopic and X-ray diffraction characterization of the nature of adsorbed arsenate on ferrihydrite. Geochim. Cosmochim. Acta 71:1643-1654. |
Junta-Rosso, J. L., M. F. Hochella, Jr. and J. D. Rimstidt. 1997. Linking microscopic and macroscopic data for heterogeneous reactions illustrated by the oxidation of Mn(II) at mineral surfaces. Geochim. Cosmochim. Acta 61:149-159. |
| Katz L.E., Hayes K.F. 1995. Surface complexation modeling II. Strategy for modeling polymer and precipitation reactions at high surface coverage. J. Colloid Interface Sci. 170:491-501. |
| Kelly S.D., Kemner K.M., Brooks S.C. 2007. X-ray absorption spectroscopy identifies calcium-oranyl-carbonate complexes at environmental concentrations. Geochim. Cosmochim. Acta 71:821-834. |
| Khare N., Martin J.D., Hesterberg D. 2007. Phosphate bonding configuration on ferrihydrite based on molecular orbital calculations and XANES fingerprinting. Geochim. Cosmochim. Acta 71:4405-4415. |
| Kim Y., Kirkpatrick R.J. 2006. B-11 NMR investigation of boron interaction with mineral surfaces: Results for boehmite, silica gel and illite. Geochim. Cosmochim. Acta 70:3231-3238. |
| *Kinyangi J., Solomon D., Liang B.I., Lerotic M., Wirick S., Lehmann J. 2006. Nanoscale biogeocomplexity of the organomineral assemblage in soil: Application of STXM microscopy and C 1s-NEXAFS spectroscopy. Soil Sci. Soc. Am. J 70:1708-1718. |
| Kubicki, J.D., K.P. Paul, and D. L. Sparks. 2008. Periodic density functional theory calculations of bulk and the (010) surface of goethite. Geochemical Transactions 9:4. |
| Lee Y.J., Elzinga E.J., Reeder R.J. 2005. Sorption mechanisms of zinc on hydroxyapatite: Systematic uptake studies and EXAFS spectroscopy analysis. Environ. Sci. Technol. 39:4042-4048. |
| Lee, S, J.A. Dyer, D. L. Sparks, N. C. Scrivner and E.J. Elzinga. 2006. A multi-scale assessment of Pb(II) sorption on dolomite. J. Colloid Interface Sci. 298:20-30. |
| Lee S.S., Nagy K.L., Park C., Fenter P. 2011. Heavy metal sorption at the muscovite (001) - fulvic acid interface. Environmental Science & Technology 45:9574-9581. |
| Liu Y.T., Wang M.K., Chen T.Y., Chiang P.N., Huang P.M., Lee J.F. 2006. Arsenate sorption on lithium/aluminum layered double hydroxide intercalated by chloride and on gibbsite: Sorption isotherms, envelopes, and spectroscopic studies. Environ. Sci. Technol. 40:7784-7789. |
| Luo L., Zhang S., Christie P. 2010. New insights into the influence of heavy metals on phenanthrene sorption in soils. Environmental Science & Technology 44:7846-7851. |
| Luxton T.R., Tadanier C.J., Eick M.J. 2006. Mobilization of arsenite by competitive interaction with silicic acid. Soil Sci. Soc. Am. J 70:204-214. |
| Madden A.S., Hochella M.F., Luxton T.P. 2006. Insights for size-dependent reactivity of hematite nanomineral surfaces through Cu2+ sorption. Geochim. Cosmochim. Acta 70:4095-4104. |
| Manning B.A., Kiser J.R., Kwon H., Kanel S.R. 2007. Spectroscopic investigation of Cr(III)- and Cr(VI)-treated nanoscale zerovalent iron. Environ. Sci. Technol. 41:586-592. |
| Masue Y., Loeppert R.H., Kramer T.A. 2007. Arsenate and arsenite adsorption and desorption behavior on coprecipitated aluminum : iron hydroxides. Environ. Sci. Technol. 41:837-842. |
Matocha, C. J., E. J. Elzinga, and D. L. Sparks. 2001. Reactivity of Pb(II) at the Mn(III,IV) (oxyhydr)oxide-water interface. Environ. Sci. Tech.35: 2967 -2972. |
| Miller A.W., Rodriguez D.R., Honeyman B.D. 2010. Upscaling sorption/desorption processes in reactive transport models to describe metal/radionuclide transport: a critical review. Environmental Science & Technology 44:7996-8007. |
| Morin G., Ona-Nguema G., Wang Y.H., Menguy N., Juillot F., Proux O., Guyot F., Calas G., Brown G.E. 2008. Extended X-ray absorption fine structure analysis of arsenite and arsenate adsorption on maghemite. Environ. Sci. Technol. 42:2361-2366. |
| Nachtegaal, M. and D.L. Sparks. 2004. Effect of iron oxide coatings on zinc sorption mechanisms at the clay-mineral/water interface. J. Colloid Interf. Sci. 276:13-23. |
| Ona-Nguema G., Morin G., Wang Y.H., Menguy N., Juillot F., Olivi L., Aquilanti G., Abdelmoula M., Ruby C., Bargar J.R., Guyot F., Calas G., Brown G.E. 2009. Arsenite sequestration at the surface of nano-Fe(OH)(2), ferrous-carbonate hydroxide, and green-rust after bioreduction of arsenic-sorbed lepidocrocite by Shewanella putrefaciens. Geochim. Cosmochim. Acta 73:1359-1381. |
Papelis, C. and K. F. Hayes. 1995. Distinguishing between interlayer and external sorption sites of clay minerals using x-ray absorption spectroscopy. Colloids Surfaces A: Physicochem. Eng. Aspects. 107:89-96. |
| Pasilis S.P., Pemberton J.E. 2008. Spectroscopic investigation of uranyl(VI) and citrate coadsorption to Al2O3. Geochim. Cosmochim. Acta 72:277-287. |
| Paul, K.W., M.J. Borda, J.D. Kubicki, and D.L. Sparks. 2005. Effect of dehydration on sulfate coordination and speciation at the Fe-(Hydr)oxide-water interface: A molecular orbital/density functional theory and Fourier transform infrared spectroscopic investigation. Langmuir 21:11071-11078. |
| Paul, K.P., J.D. Kubicki and D. L. Sparks. 2006. Quantum chemical calculations of sulfate adsorption at the Al- and Fe-(Hydr)oxide-H2O interface-Estimation of Gibbs free energies. Environ. Sci. Technol. 40:7717 -7724. |
Peak, D., R.G. Ford, and D.L. Sparks. 1999. An in-situ ATR-FTIR investigation of sulfate bonding mechanisms on goethite. J. Colloid Interf. Sci. 218:289-299. |
Peak, D., G.W. Luther, and D.L. Sparks. 2003. ATR-FTIR spectroscopic studies of boric acid adsorption on hydrous ferric oxide. Geochim. Cosmochim. Acta 67:2551-2560. |
| Pignatello J.J., Kwon S., Lu Y. 2006. Effect of Natural Organic Substances on the Surface and Adsorptive Properties of Environmental Black Carbon (Char): Attenuation of Surface Activity by Humic and Fulvic Acids. Environ. Sci. Technol. 40:7757-7763. |
| Pokrovsky O.S., Pokrovski G.S., Schott J., Galy A. 2006. Experimental study of germanium adsorption on goethite and germanium coprecipitation with iron hydroxide: X-ray absorption fine structure and macroscopic characterization. Geochim. Cosmochim. Acta 70:3325-3341. |
| Ritter K., Aiken G.R., Ranville J.F., Bauer M., Macalady D.L. 2006. Evidence for the aquatic binding of arsenate by natural organic matter-suspended Fe(III). Environ. Sci. Technol. 40:5380-5387. |
Roberts, D.R., R.G. Ford, and D.L. Sparks. 2003. Kinetics and mechanisms of Zn complexation on metal oxides using EXAFS spectroscopy. J. Colloid Interface Sci. 263:364-376. |
| Root R.A., Dixit S., Campbell K.M., Jew A.D., Hering J.G., O'Day P.A. 2007. Arsenic sequestration by sorption processes in high-iron sediments. Geochim. Cosmochim. Acta 71:5782-5803. |
| Rouff A.A., Elzinga E.J., Reeder R.J. 2006. The effect of aging and pH on Pb(II) sorption processes at the calcite - Water interface. Environ. Sci. Technol. 40:1792-1798. |
| Saha U.K., Kozak L.M., Huang P.M. 2007. Kinetics of citrate-induced selenite desorption from montmorillonite as affected by complexation with hydroxyaluminum and hydroxyaluminosilicate ions. Clays and Clay Minerals 55:71-88. |
| Sahai N., Carroll S.A., Roberts S., O'Day P.A. 2000. X-ray absorption spectroscopy of strontium(II) coordination - II. Sorption and precipitation at kaolinite, amorphous silica, and goethite surfaces. J. Colloid Interface Sci. 222:198-212. |
| Sahai N., Lee Y.J., Xu H.F., Ciardelli M., Gaillard J.F. 2007. Role of Fe(II) and phosphate in arsenic uptake by coprecipitation. Geochim. Cosmochim. Acta 71:3193-3210. |
| Scheckel, K. G. and D. L. Sparks. 2001. Temperature effects on nickel sorption kinetics at the mineral–water interface. Soil Sci. Soc. Am. J. 65:685-694. |
| Schlegel M.L., Reiller P., Mercier-Bion F., Barre N., Moulin V. 2006. Molecular environment of iodine in naturally iodinated humic substances: Insight from X-ray absorption spectroscopy. Geochim. Cosmochim. Acta 70:5536-5551. |
| Schlegel M.L., Manceau A. 2007. Zn incorporation in hydroxy-Al- and Keggin Al-13-intercalated montmorillonite: A powder and polarized EXAFS study. Environ. Sci. Technol. 41:1942-1948. |
| Scheidegger, A.M., M. Fendorf, and D.L. Sparks. 1996. Mechanisms of nickel sorption on pyrophyllite: Macroscopic and microscopic approaches. Soil Sci. Soc. Am. J. 60:1763-1772. |
| Schuurmann G., Ebert R.U., Kuhne R. 2006. Prediction of the sorption of organic compounds into soil organic matter from molecular structure. Environ. Sci. Technol. 40:7005-7011. |
| Serrano S., O'Day P.A., Vlassopoulos D., Garcia-Gonzalez M.T., Garrido F. 2009. A surface complexation and ion exchange model of Pb and Cd competitive sorption on natural soils. Geochim. Cosmochim. Acta 73:543-558. |
| Sheng G., Yang S., Sheng J., Hu J., Tan X., Wang X. 2011. Macroscopic and microscopic investigation of Ni(ii) sequestration on diatomite by batch, XPS, and EXAFS techniques. Environmental Science & Technology 45:7718-7726. |
| Sherman D.M., Peacock C.L., Hubbard C.G. 2008. Surface complexation of U(VI) on goethite (α-FeOOH). Geochim. Cosmochim. Acta 72:298-310. |
| *Shimizu M., Arai Y., Sparks D.L. 2011. Multiscale assessment of methylarsenic reactivity in soil. 1. Sorption and desorption on soils. Environmental Science & Technology 45:4293-4299. |
| Singer D.M., Johnson S.B., Catalano J.G., Farges F., Brown G.E. 2008. Sequestration of Sr(II) by calcium oxalate - A batch uptake study and EXAFS analysis of model compounds and reaction products. Geochim. Cosmochim. Acta 72:5055-5069. |
| Skyllberg U., Bloom P.R., Qian J., Lin C.M., Bleam W.F. 2006. Complexation of mercury(II) in soil organic matter: EXAFS evidence for linear two-coordination with reduced sulfur groups. Environ. Sci. Technol. 40:4174-4180. |
| *Sparks D.L. 2005. Toxic metals in the environment: The role of surfaces. Elements 1:193-197. |
| Sparks, D.L. 2005. Sorption | Metals. In Encyclopedia of Soils in the Environment, p. 532-537. D. Hillel, J.L. Hatfield, D.S. Powlson, C. Rosenweig, K.M. Scow, M.J. Singer and D.L. Sparks, eds. Elsevier Ltd., Oxford UK. |
| Stumpf S., Stumpf T., Dardenne K., Hennig C., Foerstendorf H., Klenze R., Fanghanel T. 2006. Sorption of Am(III) onto 6-line- ferrihydrite and its alteration products: Investigations by EXAFS. Environ. Sci. Technol. 40:3522-3528. |
| Sverjensky D.A. 2006. Prediction of the speciation of alkaline earths adsorbed on mineral surfaces in salt solutions. Geochim. Cosmochim. Acta 70:2427-2453. |
| Sverjensky D.A., Fukushi K. 2006. A predictive model (ETLM) for As(III) adsorption and surface speciation on oxides consistent with spectroscopic data. Geochim. Cosmochim. Acta 70:3778-3802. |
| Sverjensky D.A., Jonsson C.M., Jonsson C.L., Cleaves H.J., Hazen R.M. 2008. Glutamate surface speciation on amorphous titanium dioxide and hydrous ferric oxide. Environ. Sci. Technol. 42:6034-6039. |
| Tokoro C., Yatsugi Y., Koga H., Owada S. 2009. Sorption mechanisms of arsenate during coprecipitation with ferrihydrite in aqueous solution. Environmental Science & Technology 44:638-643. |
| Toner, B., A. Manceau, S.M. Webb, and G. Sposito. 2006. Zinc sorption to biogenic hexagonal-birnessite particles within a hydrated bacterial biofilm. Geochim. Cosmochim. Acta 70:27-43. |
| Trivedi P., Axe L., Tyson T.A. 2001. An analysis of zinc sorption to amorphous versus crystalline iron oxides using XAS. J. Colloid Interface Sci. 244:230-238. |
| Trivedi P., Axe L., Tyson T.A. 2001. XAS studies of Ni and Zn sorbed to hydrous manganese oxide. Environ. Sci. Technol. 35:4515-4521. |
| Ulrich K.U., Rossberg A., Foerstendorf H., Zanker H., Scheinost A.C. 2006. Molecular characterization of uranium(VI) sorption complexes on iron(III)-rich acid mine water colloids. Geochim. Cosmochim. Acta 70:5469-5487. |
| Wang X., Shu L., Wang Y., Xu B., Bai Y., Tao S., Xing B. 2011. Sorption of peat humic acids to multi-walled carbon nanotubes. Environmental Science & Technology 45:9276-9283. |
| Wang X., Guo X., Yang Y., Tao S., Xing B. 2011. Sorption mechanisms of phenanthrene, lindane, and atrazine with various humic acid fractions from a single soil sample. Environmental Science & Technology 45:2124-2130. |
| Wang Y., Morin G., Ona-Nguema G., Juillot F., Calas G., Brown G.E. 2011. Distinctive arsenic(V) trapping modes by magnetite nanoparticles induced by different sorption processes. Environmental Science & Technology 45:7258-7266. |
| Webb S.M., Fuller C.C., Tebo B.M., Bargar J.R. 2006. Determination of uranyl incorporation into biogenic manganese oxides using X-ray absorption spectroscopy and scattering. Environ. Sci. Technol. 40:771-777. |
| Weber T., Allard T., Tipping E., Benedetti M.F. 2006. Modeling iron binding to organic matter. Environ. Sci. Technol. 40:7488-7493. |
| Weng L.P., VanRiemsdijk W.H., Koopal L.K., Hiemstra T. 2006. Adsorption of humic substances on goethite: Comparison between humic acids and fulvic acids. Environ. Sci. Technol. 40:7494-7500. |
| Wieland E., Tits J., Kunz D., Daehn R. 2008. Strontium uptake by cementitious materials. Environ. Sci. Technol. 42:403-409. |
| Xu D.N., Peak D. 2007. Adsorption of boric acid on pure and humic acid coated am-Al(OH)(3): A boron K-edge XANES study. Environ. Sci. Technol. 41:903-908. |
| Xu, N., M.F. Hochella, Jr., G. E. Brown, Jr., and G.A. Parks. 1996. Co(II) sorption at the calcite-water interface: I. X-ray photoelectron spectroscopic study. Geochim. Cosmochim. Acta 60:2801-2815. |
| Xu Y., Axe L., Yee N., Dyer J.A. 2006. Bidentate complexation modeling of heavy metal adsorption and competition on goethite. Environ. Sci. Technol. 40:2213-2218. |
| Yu G., Saha U.K., Kozak L.M., Huang P.M. 2006. Kinetics of cadmium adsorption on aluminum precipitation products formed under the influence of tannate. Geochim. Cosmochim. Acta 70:5134-5145. |
| Zhu M., Ginder-Vogel M., Sparks D.L. 2010. Ni(II) sorption on biogenic Mn-oxides with varying Mn octahedral layer structure. Environmental Science & Technology 44:4472-4478. |
Precipitation/Dissolution |
| Allada R.K., Navrotsky A., Berbeco H.T., Casey W.H. 2002. Thermochemistry and aqueous solubilities of hydrotalcite-like solids. Science 296:721-723. |
*Allada, R.k., E. Peltier, A. Navrotsky, W.H. Casey, A. Johnson, H. Thompson-Berbeco, D.L. Sparks. 2006. Calorimetric determination of the enthalpies of formation of hyrdotalcite-like solids and their use in the geochemical modeling of metals in natural waters. Clays Clay Min. 54:409-417. |
| Brantley S.L. 2008. Kinetics of Mineral Dissolution, In Kinetics of Water-Rock Interaction. pp. 151-210. |
| Dahn R., Jullien M., Scheidegger A.M., Poinssot C., Baeyens B., Bradbury M.H. 2006. Identification of neoformed Ni-phyllosilicates upon Ni uptake in montmorillonite: A transmission electron microscopy and extended X-ray absorption fine structure study. Clays and Clay Minerals 54:209-219. |
| Dove P.M., M.F.Hochella, Jr., R.J Reeder. 1992. In situ investigation of near-equilibrium calcite precipitation by atomic force microscopy, in: Y. K. Kharaka and A. S. Maest (Eds.), Water-Rock Interaction VII, A. A. Balkema, Rotterdam. pp. 141-144. |
| Duckworth O.W., Martin S.T. 2003. Connections between surface complexation and geometric models of mineral dissolution investigated for rhodochrosite. Geochim. Cosmochim. Acta 67:1787-1801. |
| Elzinga, E.J., and R.J. Reeder. 2002. X-ray absorption spectroscopy study of Cu2+ and Zn2+ adsorption complexes at the calcite surface: Implications for site-specific metal incorporation preferences during calcite crystal growth. Geochim. Cosmochim. Acta 66:3943-3954. |
Fendorf, S. E., M. Fendorf, D. L. Sparks and R. Gronsky. 1992. Inhibitory mechanisms of Cr(III) oxidation by δ-MnO2. J. Colloid and Interface Sci., 153:37-54. |
Feng X.H., Zhu M., Ginder-Vogel M., Ni C., Parikh S.J., Sparks D.L. 2010. Formation of nano-crystalline todorokite from biogenic Mn oxides. Geochimica et Cosmochimica Acta 74:3232-3245. |
*Gräfe, M., M. Nachtegaal, and D.L. Sparks. 2004. Formation of metal-arsenate precipitates at the goethite-water interface. Environ. Sci. Technol. 38:6561-6570. |
| Jacquat O., Voegelin A., Villard A., Marcus M.A., Kretzschmar R. 2008. Formation of Zn-rich phyllosilicate, Zn-layered double hydroxide and hydrozincite in contaminated calcareous soils. Geochim. Cosmochim. Acta 72:5037-5054. |
| Jia Y.F., Xu L.Y., Fang Z., Demopoulos G.P. 2006. Observation of surface precipitation of arsenate on ferrihydrite. Environ. Sci. Technol. 40:3248-3253. |
Johnson, C.A., and F.P. Glasser. 2003. Hydrotalcite-like minerals (M2Al(OH)6(CO3)0.5.XH2O, where M = Mg, Zn, Co, Ni) in the environment: Synthesis, characterization and thermodynamic stability. Clays Clay Min. 51:1-8. |
| Lee Y.J., Reeder R.J. 2006. The role of citrate and phthalate during Co(II) coprecipitation with calcite. Geochim. Cosmochim. Acta 70:2253-2263. |
| *Livi, K. J. T. , G. S. Senesi, A. C. Scheinost and D.L. Sparks. 2009. Microscopic examination of nanosized mixed Ni−Al hydroxide surface precipitates on pyrophyllite. Environ. Sci. Technol. 43: 1299–1304. |
Nachtegaal, M. and D. L. Sparks. 2003. Nickel sequestration in a kaolinite-humic acid complex.Environ. Sci. Technol. 37: 529 -534. |
Nachtegaal, M., and D.L. Sparks. 2004. Effect of iron oxide coatings on zinc sorption mechanisms at the clay-mineral/water interface. J. Colloid and Interface Sci. 276:13-23. |
| *O'Day, P.A., G.E. Brown, Jr. and G.A. Parks. 1994. X-ray absorption spectroscopy of cobalt(II) multinuclear surface complexes and surface precipitates on kaolinite. J. Colloid Interface Sci. 165: 269-289. |
*Peltier, E., N. van der Lelie, and D.L. Sparks. 2009. Formation and stability of Ni-Al hydroxide phases in soils. Environ. Sci. Technol. 44(1):302-308. |
| *Peltier, E.., R. Allada, A. Navrotsky and D. L. Sparks. 2006. Nickel solubility and precipitation in soils: a thermodynamic study. Clays and Clay Min. 54:153-163. |
Reichard P.U., Kretzschmar R., Kraemer S.M. 2007. Dissolution mechanisms of goethite in the presence of siderophores and organic acids. Geochim. Cosmochim. Acta 71:5635-5650. |
| Scheckel, K. G., and D. L. Sparks. 2000. Kinetics of the formation and dissolution of Ni precipitates in a gibbsite/amorphous silica mixture. J. Colloid Interf. Sci. 229:222-239. |
*SCHECKEL, K. G., A. C. SCHEINOST, R. G. FORD, AND D. L. SPARKS. 2000. STABILITY OF LAYERED NI HYDROXIDE SURFACE PRECIPITATES-A DISSOLUTION KINETICS STUDY. GEOCHIM. COSMOCHIM. ACTA 64:2727-2735. |
Scheidegger, A. M., G. M. Lamble and D. L. Sparks. 1997. Spectroscopic evidence for the formation of mixed-cation hydroxide phases upon metal sorption on clays and aluminum oxides. J. Colloid Interface Sci. 186:118-128. |
*Scheidegger, A. M., D. L. Strawn, G. M. Lamble and D. L. Sparks. 1998. The kinetics of mixed Ni-Al hydroxide formation on clay and aluminum oxide minerals: A time-resolved XAFS study. Geochim. Cosmochim. Acta 62:2233-2245. |
| Scheinost, A.C., R.G. Ford, and D.L. Sparks. 1999. The role of Al in the formation of secondary Ni precipitates on pyrophyllite, gibbsite, talc, and amorphous silica: A DRS Study. Geochim. Cosmochim. Acta 63:3193-3203. |
| Scheinost, A. C., and D. L. Sparks. 2000. Formation of layered single- and double-metal hydroxide precipitates at the mineral/water interface: A multiple-scattering XAFS analysis. J. Colloid Interf. Sci. 223:167-178. |
| Schlegel M.L., A. Manceau. 2006. Evidence for the nucleation and epitaxial growth of Zn phyllosilicate on montmorillonite. Geochim. Cosmochim. Acta 70:901-917. |
Thompson, H. A., G. A. Parks and G. E. Brown, Jr. 1999. Dynamic interactions of dissolution, surface adsorption, and precipitation in an aging cobalt(II)-clay-water system. Geochim. Cosmochim. Acta 63:1767-1779. |
| Thompson, H. A., G. A. Parks and G. E. Brown, Jr. 1999. Ambient-temperature synthesis, evolution, and characterization of cobalt-aluminum hydrotalcite-like solids. Clays and Clay Minerals 47:425-438. |
| Thompson, H. A., G. A. Parks and G. E. Brown, Jr. 2000. Formation and release of cobalt(II) sorption and precipitation products in aging kaolinite-water slurries J. Colloid Interface Sci. 222:241-253. |
| Towle S.N., J.R. Bargar, G.E. Brown, Jr., and G.A. Parks. 1997. Surface precipitation of Co(II) (aq) on Al2O3. J. Colloid Interface Sci. 187:62-82. |
| Towle S.N., J.R. Bargar, G.E. Brown, Jr., and G.A. Parks. 1999. Sorption of Co(II) on metal oxide surfaces II. Identification of Co(II)(aq) adsorption sites on the (0001) and (1(1)over-bar02) surfaces of alpha-Al2O3 by grazing-incidence XAFS spectroscopy. J. Colloid Interface Sci. 217:312-321. |
| Trainor T.P., G.E. Brown, Jr., and G.A. Parks.2000. Adsorption and precipitaton of aqueous Zn(II) on alumina powders. J. Colloid Interface Sci. 231:359-372. |
| Trainor T.P., Fitts J.P., Templeton A.S., Grolimund D., Brown G.E. 2001. Grazing-incidence XAFS study of aqueous Zn(II) sorption on α-Al2O3 single crystals. J. Colloid Interface Sci. 244:239-244. |
| *Voegelin, A., and R. Kretzschmar. 2005. Formation and dissolution of single and mixed Zn and Ni precipitates in soil: Evidence from column experiments and extended X-ray absorption fine structure spectroscopy. Environ. Sci. Technol. 39:5311-5318. |
| Violante A., Ricciardella M., Del Gaudio S., Pigna M. 2006. Coprecipitation of arsenate with metal oxides: Nature, mineralogy, and reactivity of aluminum precipitates. Environ. Sci. Technol. 40:4961-4967. |
| Xia K., Mehadi A., Taylor R.W., Bleam W.F. 1997. X-ray absorption and electron paramagnetic resonance studies of Cu(II) sorbed to silica: Surface-induced precipitation at low surface coverages. J. Colloid Interface Sci. 185:252-257. |
| Yamaguchi, N. U., A. C. Scheinost and D. L. Sparks. 2001. Surface-induced nickel hydroxide precipitation in the presence of citrate and salicylate. Soil Sci. Soc. Am. J. 65:729-736. |
Speciation of Contaminants in Plants and Soils |
| Ajiboye B., Akinremi O.O., Jurgensen A. 2007. Experimental validation of quantitative XANES analysis for phosphorus speciation. Soil Sci. Soc. Am. J 71:1288-1291. |
| Al-Abed S.R., Jegadeesan G., Scheckel K.G., Tolaymat T. 2008. Speciation, characterization, and mobility of As, Se, and Hg in flue gas desulphurization residues. Environ. Sci. Technol. 42:1693-1698. |
*Arai, Y., A. Lanzirotti, S. Sutton, J.A. Davis, and D.L. Sparks. 2003. Arsenic speciation and reactivity in poultry litter. Environ. Sci. Technol. 37:4083-4090. |
| Arai, Y., A. Lanzirotti, S.R. Sutton, M. Newville, J. Dyer, and D.L. Sparks. 2006. Spatial and temporal variability of arsenic solid-state speciation in historically lead arsenate contaminated soils. Environ. Sci. Technol. 40:673-679. |
| Arai Y., McBeath M., Bargar J.R., Joye J., Davis J.A. 2006. Uranyl adsorption and surface speciation at the imogolite-water interface: Self-consistent spectroscopic and surface complexation models. Geochim. Cosmochim. Acta 70:2492-2509. |
| Arai Y., Marcus M.K., Tamura N., Davis J.A., Zachara J.M. 2007. Spectroscopic evidence for uranium bearing precipitates in vadose zone sediments at the Hanford 300-area site. Environ. Sci. Technol. 41:4633-4639. |
| Arai Y., Moran P.B., Honeyman B.D., Davis J.A. 2007. In situ spectroscopic evidence for neptunium(V)-carbonate inner-sphere and outer-sphere ternary surface complexes on hematite surfaces. Environ. Sci. Technol. 41:3940-3944. |
| Bank S., Bank J.F., Marchetti P.S., Ellis P.D. 1989. Solid-state cadmium-113 nuclear magnetic-resonance study of cadmium speciation in environmentally contaminated sediments. Journal of Environmental Quality 18:25-30. |
| Beak D.G., Basta N.T., Scheckel K.G., Traina S.J. 2008. Linking solid phase speciation of Pb sequestered to birnessite to oral Pb bioaccessibility: Implications for soil remediation. Environ. Sci. Technol. 42:779-785. |
| Beak D.G., Wilkin R.T., Ford R.G., Kelly S.D. 2008. Examination of arsenic speciation in sulfidic solutions using X-ray absorption spectroscopy. Environ. Sci. Technol. 42:1643-1650. |
| Beauchemin S., Hesterberg D., Chou J., Beauchemin M., Simard R.R., Sayers D.E. 2003. Speciation of phosphorus in phosphorus-enriched agricultural soils using X-ray absorption near-edge structure spectroscopy and chemical fractionation. Journal of Environmental Quality 32:1809-1819. |
| Bernaus A., Gaona X., Esbri J.M., Higueras P., Falkenberg G., Valiente M. 2006. Microprobe techniques for speciation analysis and geochemical characterization of mine environments: The mercury district of Almaden in Spain. Environ. Sci. Technol. 40:4090-4095. |
| Bertsch P.M., Hunter D.B., Sutton S.R., Bajt S., Rivers M.L. 1994. In situ chemical speciation of uranium in soils and sediments by micro x-ray absorption spectroscopy. Environ. Sci. Technol. 28:980-984. |
Blute, N.K., D.J. Brabander, H.F. Hemond, S.R. Sutton, M.G. Newville, and M.L. Rivers. 2004. Arsenic sequestration by ferric iron plaque on cattail roots. Environ. Sci. Technol. 38:6074-6077. |
| Booth B. 2008. Arsenic speciation varies with type of rice. Environ. Sci. Technol. 42:3481-3906. |
| Catalano J.G., Heald S.M., Zachara J.M., Brown G.E. 2004. Spectroscopic and diffraction study of uranium speciation in contaminated vadose zone sediments from the Hanford site, Washington state. Environ. Sci. Technol. 38:2822-2828. |
| Catalano J.G., McKinley J.P., Zachara J.M., Heald S.M., Smith S.C., Brown G.E. 2006. Changes in uranium speciation through a depth sequence of contaminated Hanford sediments. Environ. Sci. Technol. 40:2517-2524. |
| Choi S., O'Day P.A., Rivera N.A., Mueller K.T., Vairavamurthy M.A., Seraphin S., Chorover J. 2006. Strontium speciation during reaction of kaolinite with simulated tank-waste leachate: Bulk and microfocused EXAFS analysis. Environ. Sci. Technol. 40:2608-2614. |
| De La Rosa G., Parsons J.G., Martinez-Martinez A., Peralta-Videa J.R., Gardea-Torresdey J.L. 2006. Spectroscopic study of the impact of arsenic speciation on arsenic/phosphorus uptake and plant growth in tumbleweed (Salsola kali) Environ. Sci. Technol.. 40:1991-1996. |
| DeVolder P.S., Brown S.L., Hesterberg D., Pandya K. 2003. Metal bioavailability and speciation in a wetland tailings repository amended with biosolids compost, wood ash, and sulfate. Journal of Environmental Quality 32:851-864. |
| Dolsch E., Basile-Dolsch I., Rose J., Masion A., Borschneck D., Hazemann J.L., SaintMacary H., Bottero J.Y. 2006. New combination of EXAFS spectroscopy and density fractionation for the speciation of chromium within an andosol. Environ. Sci. Technol. 40:7602-7608. |
| Donner E., Howard D.L., Jonge M.D.d., Paterson D., Cheah M.H., Naidu R., Lombi E. 2011. X-ray absorption and micro x-ray fluorescence spectroscopy investigation of copper and zinc speciation in biosolids. Environmental Science & Technology 45:7249-7257. |
| Essilfie-Dughan J., Pickering I.J., Hendry M.J., George G.N., Kotzer T. 2010. Molybdenum speciation in uranium mine tailings using x-ray absorption spectroscopy. Environmental Science & Technology 45:455-460. |
| Everhart J.L., McNear D., Peltier E., van der Lelie D., Chaney R.L., Sparks D.L. 2006. Assessing nickel bioavailability in smelter-contaminated soils. Science of the Total Environment 367:732-744. |
*Fendorf S., Michael H.A., van Geen A. 2010. Spatial and temporal variations of groundwater arsenic in South and Southeast Asia. Science 328:1123-1127. |
| Foster A.L., Brown G.E., Parks G.A., Tingle T.N., Voigt D.E., Brantley S.L. 1997. XAFS determination of As(V) associated with Fe(III) oxyhydroxides in weathered mine tailings and contaminated soil from California, USA. Journal De Physique Iv 7:815-816. |
| Foster A.L., Brown G.E., Tingle T.N., Parks G.A. 1998. Quantitative arsenic speciation in mine tailings using X-ray absorption spectroscopy. American Mineralogist 83:553-568. |
| Goldberg S., Johnston C.T. 2001. Mechanisms of arsenic adsorption on amorphous oxides evaluated using macroscopic measurements, vibrational spectroscopy, and surface complexation modeling. J. Colloid Interface Sci. 234:204-216. |
| Gräfe, M. and D. L. Sparks. 2006. Solid phase speciation of arsenic, p. 75-91, In Managing Arsenic in the Environment: From Soil to Human Health, R. Naidu, E. Smith, G. Owens, P. Bhattacharya and P. Nadebaum, eds., CSIRO Publishing, Collingwood, Victoria, Australia. |
| Gräfe, M., R.V. Tappero, M. A. Marcus, and D. L. Sparks. 2008. Arsenic speciation in multiple metal environments: I. Bulk-XAFS spectroscopy of model and mixed compounds. J. Colloid Interface Sci. 320:383-399. |
| Gräfe, M., R.V. Tappero, M. A. Marcus, and D. L. Sparks. 2008. Arsenic speciation in multiple metal environments: II. Micro-spectroscopic investigation of a CCA contaminated soil. J. Colloid Interface Sci. 321:1-20. |
*Hansel, C.M., S. Fendorf, S. Sutton and M. Newville. 2001. Characterization of Fe plaque and associated metals on the roots of mine-waste impacted aquatic plants. Environ. Sci. Technol. 35:3863-3868. |
| Hayes S.M., O' Day P.A., Webb S.M., Maier R.M., Chorover J. 2011. Changes in zinc speciation with mine tailings acidification in a semiarid weathering environment. Environmental Science & Technology 45:7166-7172. |
| He Z.Q., Honeycutt C.W., Zhang T.Q., Pellechia P.J., Caliebe W.A. 2007. Distinction of metal species of phytate by solid-state spectroscopic techniques. Soil Sci. Soc. Am. J 71:940-943. |
Hunger, S., H. Cho, J.T. Sims, and D.L. Sparks. 2004. Direct speciation of phosphorus in alum-amended poultry litter: Solid-state P-31 NMR investigation. Environ. Sci. Technol. 38:674-681. |
| *Hunger, S.J., J.T. Sims and D. L. Sparks. 2008. Evidence for struvite in poultry litter: Effect of storage and drying. J. Environ. Qual. 37: 1617-1625. |
| Jacobson A.R., Dousset S., Andreux F., Baveye P.C. 2007. Electron microprobe and synchrotron X-ray fluorescence mapping of the heterogeneous distribution of copper in high-copper vineyard soils. Environ. Sci. Technol. 41:6343-6349. |
| Jacquat O., Voegelin A., Villard A., Marcus M.A., Kretzschmar R. 2008. Formation of Zn-rich phyllosilicate, Zn-layered double hydroxide and hydrozincite in contaminated calcareous soils. Geochim. Cosmochim. Acta 72:5037-5054. |
| Kachenko A.G., Grafe M., Singh B., Heald S.M. 2010. Arsenic speciation in tissues of the hyperaccumulator P. calomelanos var. austroamericana using x-ray absorption spectroscopy. Environmental Science & Technology 44:4735-4740. |
| Karlsson T., Skyllberg U. 2007. Complexation of zinc in organic soils - EXAFS evidence for sulfur associations. Environ. Sci. Technol. 41:119-124. |
| Karlsson T., Persson P., Skyllberg U., Morth C.M., Giesler R. 2008. Characterization of iron(III) in organic soils using extended X-ray absorption fine structure spectroscopy. Environ. Sci. Technol. 42:5449-5454. |
| Kelly S.D., Kemner K.M., Carley J., Criddle C., Jardine P.M., Marsh T.L., Phillips D., Watson D., Wu W.M. 2008. Speciation of uranium in sediments before and after in situ biostimulation. Environ. Sci. Technol. 42:1558-1564. |
| Khan B.I., Solo-Gabriele H.M., Townsend T.G., Cai Y. 2006. Release of arsenic to the environment from CCA-treated wood. 1. Leaching and speciation during service. Environ. Sci. Technol. 40:988-993. |
| *Khaokaew S., Chaney R.L., Landrot G., Ginder-Vogel M., Sparks D.L. 2011. Speciation and release kinetics of cadmium in an alkaline paddy soil under various flooding periods and draining conditions. Environmental Science & Technology 45:4249-4255. |
| Khan B.I., Jambeck J., Solo-Gabriele H.M., Townsend T.G., Cai Y. 2006. Release of arsenic to the environment from CCA-treated wood. 2. Leaching and speciation during disposal. Environ. Sci. Technol. 40:994-999. |
| Kirpichtchikova T.A., Manceau A., Spadini L., Panfili F., MarcuS M.A., Jacquet T. 2006. Speciation and solubility of heavy metals in contaminated soil using X-ray microfluorescence, EXAFS spectroscopy, chemical extraction, and thermodynamic modeling. Geochim. Cosmochim. Acta 70:2163-2190. |
| Kuwabara J.S., Arai Y., Topping B.R., Pickering I.J., George G.N. 2007. Mercury speciation in piscivorous fish from mining-impacted reservoirs. Environ. Sci. Technol. 41:2745. |
| Li, T., Z. Dia, X. Yanga and D.L. Sparks. 2011. Effects of dissolved organic matter from the rhizosphere of the hyperaccumulator Sedum alfredii on sorption of zinc and cadmium by different soils. J. Hazard. Mater. 192(3):1616-1622.
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| Liu W.J., Zhu Y.G., Hu Y., Williams P.N., Gualt A.G., Meharg A.A., Charnock J.M., Smith F.A. 2006. Arsenic sequestration in iron plaque, its accumulation and speciation in mature rice plants (Oryza sativa L.). Environ. Sci. Technol. 40:5730-5736. |
| Livi, K. J. T. , G. S. Senesi, A. C. Scheinost and D.L. Sparks. 2009. Microscopic examination of nanosized mixed Ni−Al hydroxide surface precipitates on pyrophyllite. Environ. Sci. Technol. 43: 1299–1304. |
| Lombi E., Scheckel K.G., Armstrong R.D., Forrester S., Cutler J.N., Paterson D. 2006. Speciation and distribution of phosphorus in a fertilized soil: A synchrotron-based investigation. Soil Sci. Soc. Am. J 70:2038-2048. |
| Malherbe J., Isaure M.-P., S. F., Watson R.P., Rodriguez-Gonzalez P., Stutzman P.E., Davis C.W., Maurizio C., Unceta N., Sieber J.R., Long S.E., Donard O.F.X. 2011. Evaluation of hexavalent chromium extraction method EPA method 3060a for soils using XANES spectroscopy. Environmental Science & Technology 45:10492-10500. |
| Makris K.C., Quazi S., Nagar R., Sarkar D., Datta R., Sylvia V.L. 2008. In vitro model improves the prediction of soil arsenic bioavailability: Worst-case scenario. Environ. Sci. Technol. 42:6278-6284. |
| Makris K.C., Quazi M., Punamiya P., Sarkar D., Datta R. 2008. Fate of arsenic in swine waste from concentrated animal feeding operations. Journal of Environmental Quality 37:1626-1633. |
Manceau, A., M.-C. Boisset, G. Sarret, J.-L. Hazemann, M. Mench, P. Cambier and R. Prost. 1996. Direct determination of lead speciation in contaminated soils by EXAFS spectroscopy. Environ. Sci. Technol. 30:1540-1552. |
Manceau, A., M. Schlegel, K. L. Nagy and L. Charlet. 1999. Evidence for the formation of trioctahedral clay upon sorption of Co2+ on quartz.J. Colloid Interf. Sci. 220:181-197. |
Manceau, A. et.al. 2000. Quantitative Zn speciation in smelter-contaminated soils by EXAFS spectroscopy. Am. J. Sci. 300:289-343. |
*Manceau, A., M.A. Marcus, N. Tamura, O. Proux, N. Geoffroy, and B. Lanson. 2004. Natural speciation of Zn at the micrometer scale in a clayey soil using X-ray fluorescence, absorption, and diffraction. Geochim. Cosmochim. Acta 68:2467-2483. |
| Manceau A., Lanson M., Geoffroy N. 2007. Natural speciation of Ni, Zn, Ba, and As in ferromanganese coatings on quartz using X-ray fluorescence, absorption, and diffraction. Geochim. Cosmochim. Acta 71:95-128. |
| Manceau A., Kersten M., Marcus M.A., Geoffroy N., Granina L. 2007. Ba and Ni speciation in a nodule of binary Mn oxide phase composition from Lake Baikal. Geochim. Cosmochim. Acta 71:1967-1981. |
| Manceau A., Nagy K.L., Marcus M.A., Lanson M., Geoffroy N., Jacquet T., Kirpichtchikova T. 2008. Formation of metallic copper manoparticles at the soil-root interface. Environ. Sci. Technol. 42:1766-1772. |
| Martinez C.E., Bazilevskaya K.A., Lanzirotti A. 2006. Zinc coordination to multiple ligand atoms in organic-rich surface soils. Environ. Sci. Technol. 40:5688-5695. |
*McNear, D.H. Jr., E. Peltier, J. Everhart, R.L. Chaney, S. Sutton, M. Newville, M. Rivers, D.L. Sparks. 2005. The application of fluoresence and absorption edge computed microtomography to image metal compartmentalization in Alyssum murale. Environ. Sci. Technol. 39:2210-2218. |
| *McNear, D.H., Jr., R.L. Chaney and D. L. Sparks. 2007. The effects of soil type and chemical treatment on nickel speciation in refinery enriched soils: A multi-technique investigation. Geochim. Cosmochim. Acta 79:2190-2208. |
| McNear, D. H. Jr. , R. L. Chaney and D.L. Sparks. 2010. The hyperaccumulator Alyssum murale uses complexation with nitrogen and oxygen donor ligands for Ni transport and storage. Phytochemistry 71:188-200.
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| Meharg A.A., Lombi E., Williams P.N., Scheckel K.G., Feldmann J., Raab A., Zhu Y.G., Islam R. 2008. Speciation and localization of arsenic in white and brown rice grains. Environ. Sci. Technol. 42:1051-1057. |
| *Nachtegaal, M., M.A. Marcus, J.E. Sonke, J. Vangronsveld, K.J.T. Livi, D. van Der Lelie, and D.L. Sparks. 2005. Effects of in situ remediation on the speciation and bioavailability of zinc in a smelter contaminated soil. Geochim. Cosmochim. Acta 69:4649-4664. |
| *Nico P.S., Ruby M.V., Lowney Y.W., Holm S.E. 2006. Chemical speciation and bioaccessibility of arsenic and chromium in chromated copper arsenate-treated wood and soils. Environ. Sci. Technol. 40:402-408. |
| Oram L.L., Strawn D.G., Marcus M.A., Fakra S.C., Moller G. 2008. Macro- and microscale investigation of selenium speciation in blackfoot river, Idaho sediments. Environ. Sci. Technol. 42:6830-6836. |
| Ostergren J.D., Brown G.E., Parks G.A., Tingle T.N. (1999) Quantitative speciation of lead in selected mine tailings from Leadville, CO. Environ. Sci. Technol. 33:1627-1636. |
| Pattanaik S., Huggins F.E., Huffman G.P., Linak W.P., Miller C.A. 2007. XAFS studies of nickel and sulfur speciation in residual oil fly-ash particulate matters (ROFA PM). Environ. Sci. Technol.. 41:1104-1110. |
*Peak, D. , J.T. Sims and D.L. Sparks. 2002. Solid-state speciation of natural and alum-amended poultry litter using XANES spectroscopy Environ. Sci. Technol.36: 4253 -4261. |
| Pickering, I.J., L. Gumaelius, H.H. Harris, R.C. Prince, G. Hirsch, J.A. Banks, D.E. Salt, and G.N. George. 2006. Localizing the biochemical transformations of arsenate in a hyperaccumulating fern. Environ. Sci. Technol. 40:5010-5014. |
| Rajan M., Darrow J., Hua M., Barnett B., Mendoza M., Greenfield B.K., Andrews J.C. 2008. Hg L-3 XANES study of mercury methylation in shredded Eichhornia crassipes. Environ. Sci. Technol. 42:5568-5573. |
Roberts, D.R. and D.L. Sparks. 2002. Zinc speciation in a smelter-contaminated soil profile using bulk and microspectroscopic techniques. Environ. Sci. Technol.36: 1742-1750. |
| Roberts L.C., Hug S.J., Dittmar J., Voegelin A., Saha G.C., Ali M.A., Badruzzanian A.B.M., Kretzschniar R. 2007. Spatial distribution and temporal variability of arsenic in irrigated rice fields in Bangladesh. 1. Irrigation water. Environ. Sci. Technol. 41:5960-5966. |
| Root R.A., Dixit S., Campbell K.M., Jew A.D., Hering J.G., O'Day P.A. 2007. Arsenic sequestration by sorption processes in high-iron sediments. Geochim. Cosmochim. Acta 71:5782-5803. |
| Ryser, A.L., D.G. Strawn, M.A. Marcus, S. Fakra, J.L. Johnson-Maynard, and G. Moller. 2006. Microscopically focused synchrotron X-ray investigation of selenium speciation in soils developing on reclaimed mine lands. Environ. Sci. Technol. 40:462-467. |
| *Sarret G., Saumitou-Laprade P., Bert V., Proux O., Hazemann J.L., Traverse A., Marcus M.A., Manceau A. 2002. Forms of zinc accumulated in the hyperaccumulator Arabidopsis halleri. Plant Physiology 130:1815-1826. |
| Sarret G.r., Saumitou-Laprade P., Bert V.r., Proux O., Hazemann J.-L., Traverse A.s., Marcus M.A., Manceau A. 2002. Forms of zinc accumulated in the hyperaccumulator Arabidopsis halleri. Plant Physiology 130:1815-1826. |
| Sarret G., Harada E., Choi Y.E., Isaure M.P., Geoffroy N., Fakra S., Marcus M.A., Birschwilks M., Clemens S., Manceau A. 2006. Trichomes of tobacco excrete zinc as zinc-substituted calcium carbonate and other zinc-containing compounds. Plant Physiology 141:1021-1034. |
Scheckel, K.G., E. Lombi, S.A. Rock, and N.J. McLaughlin. 2004. In vivo synchrotron study of thallium speciation and compartmentation in lberis intermedia. Environ. Sci. Technol. 38:5095-5100. |
| Scheidegger A.M., Vespa M., Wieland E., Harfouche M., Grolimund D., Dahn R., Jenni A., Scrivener K. 2006. Micro-scale chemical speciation of highly heterogeneous cementitious materials using synchrotron-based X-ray absorption spectroscopy. Chimia 60:149-149. |
| Scheinost A.C., Rossberg A., Vantelon D., Xifra I., Kretzschmar R., Leuz A.K., Funke H., Johnson C.A. 2006. Quantitative antimony speciation in shooting-range soils by EXAFS spectroscopy. Geochim. Cosmochim. Acta 70:3299-3312. |
| Schroth A.W., Bostick B.C., Kaste J.M., Friedland A.J. 2008. Lead sequestration and species redistribution during soil organic matter decomposition. Environ. Sci. Technol. 42:3627-3633. |
| Schuwirth N., Voegelin A., Kretzschmar R., Hofmann T. 2007. Vertical distribution and speciation of trace metals in weathering flotation residues of a zinc/lead sulfide mine. Jouranal of Environmental Quality 36:61-69. |
| *Seiter, J.M., K. E. Staats-Borda, M. Ginder-Vogel and D.L. Sparks. 2008. XANES spectroscopic analysis of phosphorus speciation in alum-amended poultry litter. J. Environ. Qual. 37:477-485. |
| *Shimizu M., Arai Y., Sparks D.L. 2011. Multiscale assessment of methylarsenic reactivity in soil. 2. Distribution and speciation in soil. Environmental Science & Technology 45:4293-4299. |
| Shober, A.L., D.L. Hesterberg, J.T. Sims, and S. Gardner. 2006. Characterization of phosphorus species in biosolids and manures using XANES spectroscopy. J. Environ. Qual. 35:1983-1993. |
| Strawn D.G., Baker L.L. 2008. Speciation of Cu in a contaminated agricultural soil measured by XAFS, μ-XAFS, and μ-XRF. Environ. Sci. Technol. 42:37-42. |
| Terzano R., Spagnuolo M., Vekemans B., Nolf W.D., Janssens K., Falkenberg G., Fiore S., Ruggiero P. 2007. Assessing the origin and fate of Cr, Ni, Cu, Zn, Pb, and V in industrial polluted soil by combined microspectroscopic techniques and bulk extraction methods. Environ. Sci. Technol. 41:6762. |
| Thakali S., Allen H.E., Di Toro D.M., Ponizovsky A.A., Rooney C.P., Zhao F.J., McGrath S.P., Criel P., Van Eeckhout H., Janssen C.R., Oorts K., Smolders E. 2006. Terrestrial biotic ligand model. 2. Application to Ni and Cu toxicities to plants, invertebrates, and microbes in soil. Environ. Sci. Technol. 40:7094-7100. |
| Tokunaga T.K., Wan J.M., Kim Y.M., Sutton S.R., Newville M., Lanzirotti A., Rao W. 2008. Real-time X-ray absorption spectroscopy of uranium, iron, and manganese in contaminated sediments during bioreduction. Environ. Sci. Technol. 42:2839-2844. |
| Utsunomiya S., Ewing R.C. 2003. Application of high-angle annular dark field scanning transmission electron microscopy, scanning transmission electron microscopy-energy dispersive X-ray spectrometry, and energy-filtered transmission electron microscopy to the characterization of nanoparticles in the environment. Environ. Sci. Technol. 37:786-791. |
| Vespa, M., R. Dahn, E. Gallucci, D. Grolimund, E. Wieland, and A.M. Scheidegger. 2006. Microscale Investigations of Ni Uptake by Cement Using a Combination of Scanning Electron Microscopy and Synchrotron-Based Techniques. Environ. Sci. Technol. 40:7702-7709. |
| Vespa M., Dahn R., Grolimund D., Wieland E., Scheidegger A.M. 2007. Co speciation in hardened cement paste: A macro- and micro-spectroscopic investigation. Environ. Sci. Technol. 41:1902-1908. |
| *Voegelin A., Weber F.A., Kretzschmar R. 2007. Distribution and speciation of arsenic around roots in a contaminated riparian floodplain soil: Micro-XRF element mapping and EXAFS spectroscopy. Geochim. Cosmochim. Acta 71:5804-5820. |
| Violante, A., M. Ricciardella, S. Del Gaudio, and M. Pigna. 2006. Coprecipitation of arsenate with metal oxides: Nature, mineralogy, and reactivity of aluminum precipitates. Environ. Sci. Technol. 40:4961-4967. |
| Werner M.L., Nico P.S., Marcus M.A., Anastasio C. 2007. Use of micro-XANES to speciate chromium in airborne fine particles in the Sacramento Valley. Environ. Sci. Technol. 41:4919-4924. |
| Wiramanaden C.I.E., Liber K., Pickering I.J. 2010. Selenium speciation in whole sediment using x-ray absorption spectroscopy and micro x-ray fluorescence imaging. Environmental Science & Technology 44:5389-5394. |
| Xu S.P., Jaffe P.R. 2006. Effects of plants on the removal of hexavalent chromium in wetland sediments. Journal of Environmental Quality 35:334-341. |
| Xu X.Y., McGrath S.P., Meharg A.A., Zhao F.J. 2008. Growing rice aerobically markedly decreases arsenic accumulation. Environ. Sci. Technol. 42:5574-5579. |
| Yoon T.H., Benzerara K., Ahn S., Luthy R.G., Tyliszczak T., Brown G.E. 2006. Nanometer-scale chemical heterogeneities of black carbon materials and their impacts on PCB sorption properties: Soft X-ray spectromicroscopy study. Environ. Sci. Technol. 40:5923-5929. |
| Zachara J.M., Ainsworth C.C., Brown G.E., Catalano J.G., McKinley J.P., Qafoku O., Smith S.C., Szecsody J.E., Traina S.J., Warner J.A. 2004. Chromium speciation and mobility in a high level nuclear waste vadose zone plume. Geochim. Cosmochim. Acta 68:13-30. |
| Zavala Y.J., Gerads R., Gurleyuk H., Duxbury J.M. 2008. Arsenic in rice: II. Arsenic speciation in USA grain and implications for human health. Environ. Sci. Technol. 42:3861-3866. |
Mineral/Microbe Interactions |
| Bargar J.R., Tebo B.M., Bergmann U., Webb S.M., Glatzel P., Chiu V.Q., Villalobos M. 2005. Biotic and abiotic products of Mn(II) oxidation by spores of the marine Bacillus sp. strain SG-1. American Mineralogist 90:143-154. |
| Bargar J.R., Fuller C.C., Marcus M.A., Brearley A.J., De la Rosa M.P., Webb S.M., Caldwell W.A. 2009. Structural characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ. Geochim. Cosmochim. Acta 73:889-910. |
| Borrok D., Fein J.B. 2004. Distribution of protons and Cd between bacterial surfaces and dissolved humic substances determined through chemical equilibrium modeling. Geochim. Cosmochim. Acta 68:3043-3052. |
*Boyanov, M.I., S.D. Kelly, K.M. Kemner, B.A. Bunker, J.B. Fein, and D.A. Fowle. 2003. Adsorption of cadmium to Bacillus subtilis bacterial cell walls: a pH-dependent X-ray absorption fine structure spectroscopy study. Geochim. Cosmochim. Acta 67:3299-3311. |
| Boyanov M.I., O'Loughlin E.J., Roden E.E., Fein J.B., Kemner K.M. 2007. Adsorption of Fe(II) and U(VI) to carboxyl-functionalized microspheres: The influence of speciation on uranyl reduction studied by titration and XAFS. Geochim. Cosmochim. Acta 71:1898-1912. |
Brown, G.E., V.E. Henrich, W.H. Casey, D.L. Clark, C. Eggleston, A. Felmy, D.W. Goodman, M. Gratzel, G. Maciel, M.I. McCarthy, K.H. Nealson, D.A. Sverjensky, M.F. Toney, and J.M. Zachara. 1999. Metal oxide surfaces and their interactions with aqueous solutions and microbial organisms. Chem. Rev. 99:77-174. |
| Brooks S.C., Fredrickson J.K., Carroll S.L., Kennedy D.W., Zachara J.M., Plymale A.E., Kelly S.D., Kemner K.M., Fendorf S. 2003. Inhihition of bacterial U(VI) reduction by calcium. Environ. Sci. Technol. 37:1850-1858. |
| Burgos W.D., McDonough J.T., Senko J.M., Zhang G.X., Dohnalkova A.C., Kelly S.D., Gorby Y., Kemner K.M. 2008. Characterization of uraninite nanoparticles produced by Shewanella oneidensis MR-1. Geochim. Cosmochim. Acta 72:4901-4915. |
| Burnett P.G.G., Daughney C.J., Peak D. 2006. Cd adsorption onto Anoxybacillus flavithermus: Surface complexation modeling and spectroscopic investigations. Geochim. Cosmochim. Acta 70:5253-5269. |
| Campbell K.M., Malasarn D., Saltikov C.W., Newman D.K., Hering J.G. 2006. Simultaneous microbial reduction of iron(III) and arsenic(V) in suspensions of hydrous ferric oxide. Environ. Sci. Technol. 40:5950-5955. |
| Casey W.H., Rustad J.R. 2007. Reaction dynamics, molecular clusters, and aqueous geochemistry. Annual Review of Earth and Planetary Sciences 35:21-46. |
| Dolsch E., Basile-Dolsch I., Rose J., Masion A., Borschneck D., Hazemann J.L., SaintMacary H., Bottero J.Y. 2006. New combination of EXAFS spectroscopy and density fractionation for the speciation of chromium within an andosol. Environ. Sci. Technol. 40:7602-7608. |
| Domagal-Goldman, S.D., K.W. Paul, D.L. Sparks and J.D. Kubicki. 2009. Quantum chemical study of the Fe(III)-desferrioxamine B siderophore complex—Electronic structure, vibrational frequencies, and equilibrium Fe-isotope fractionation. Geochim. Cosmochim. Acta 73(1):1-12. |
| Dynes J.J., Tyliszczak T., Araki T., Lawrence J.R., Swerhone G.D.W., Leppard G.G., Hitchcock A.P. 2006. Speciation and quantitative mapping of metal species in microbial biofilms using scanning transmission X-ray microscopy. Environ. Sci. Technol. 40:1556-1565. |
| Fukushi K., Sverjensky D.A. 2007. A predictive model (ETLM) for arsenate adsorption and surface speciation on oxides consistent with spectroscopic and theoretical molecular evidence. Geochim. Cosmochim. Acta 71:3717-3745. |
*Holman, H.N., K. Nieman, D.L. Sorensen, C.D. Miller, M.C. Martin, T. Borch, W.R. McKinney, and R.C. Sims. 2002. Catalysis of PAH biodegradation by humic acid shown in synchrotron infrared studies. Environ. Sci. Technol. 36:1276-1280. |
| *Huang J.-H., Elzinga E.J., Brechbuehl Y., Voegelin A., Kretzschmar R. 2011. Impacts of Shewanella putrefaciens strain CN-32 cells and extracellular polymeric substances on the sorption of As(V) and As(III) on Fe(III)-(hydr)oxides. Environmental Science & Technology 45:2804-2810. |
| *Huang J.-H., Voegelin A., Pombo S.A., Lazzaro A., Zeyer J., Kretzschmar R. 2011. Influence of arsenate adsorption to ferrihydrite, goethite, and boehmite on the kinetics of arsenate reduction by Shewanella putrefaciens strain CN-32. Environmental Science & Technology 45:7701-7709. |
| Huang P.M., Wang M.K., Chiu C.Y. 2005. Soil mineral-organic matter-microbe interactions: Impacts on biogeochemical processes and biodiversity in soils. Pedobiologia 49:609-635. |
| Johnson K.J., Cygan R.T., Fein J.B. 2006. Molecular simulations of metal adsorption to bacterial surfaces. Geochim. Cosmochim. Acta 70:5075-5088. |
Kelly, S.D., K.M. Kemner, J.B. Fein, D.A. Fowle, M.I. Boyanov, B.A. Bunker, and N. Yee. 2002. X-ray absorption fine structure determination of pH-dependent U-bacterial cell wall interactions. Geochim. Cosmochim. Acta 66:3855-3871. |
Kemner, K.M., S.D. Kelly, B. Lai, J. Maser, E.J. O'Loughlin, D. Sholto-Douglas, Z.H. Cai, M.A. Schneegurt, C.F. Kulpa, and K.H. Nealson. 2004. Elemental and redox analysis of single bacterial cells by X-ray microbeam analysis. Science 306:686-687. |
| *Kemner, K.M., E.J. O'Loughlin, S.D.Kelly, and M. I. Boyanov. 2005. Synchrotron x-ray investigations of mineral-microbe-metal interactions. Elements 1:66-70. |
| Kubicki, J.D., K.P. Paul, and D. L. Sparks. 2008. Periodic density functional theory calculations of bulk and the (010) surface of goethite. Geochemical Transactions 9:4. |
| Liu C.G., Zachara J.M., Gorby Y.A., Szecsody J.E., Brown C.F. 2001. Microbial reduction of Fe(III) and sorption/precipitation of Fe(II) on Shewanella putrefaciens strain CN32. Environ. Sci. Technol. 35:1385-1393. |
| Murray K.J., Tebo B.M. 2007. Cr(III) is indirectly oxidized by the Mn(II)-Oxidizing bacterium Bacillus sp strain SG-1. Environ. Sci. Technol. 41:528-533. |
| Naeem A., Woertz J.R., Fein J.B. 2006. Experimental measurement of proton, Cd, Pb, Sr, and Zn adsorption onto the fungal species Saccharomyces cerevisiae. Environ. Sci. Technol. 40:5724-5729. |
| Park J.M., Lee J.S., Lee J.U., Chon H.T., Jung M.C. 2006. Microbial effects on geochemical behavior of arsenic in As-contaminated sediments. Journal of Geochemical Exploration 88:134-138. |
| Paul, K. W., M. J. Borda, J. D. Kubicki, and D. L. Sparks. 2005. Effect of dehydration on sulfate coordination and speciation at the Fe-(Hydr)oxide-water interface: A molecular orbital/density functional theory and Fourier Transform Infrared Spectroscopic investigation. Langmuir 21:11071-11078. |
| Paul, K.W., J.D. Kubicki and D. L. Sparks. 2007. Sulphate adsorption at the Fe (hydr)oxide–H2O interface: comparison of cluster and periodic slab DFT predictions, European J Soil Sci. 58:978-988. |
| Peña J., Bargar J.R., Sposito G. 2011. Role of bacterial biomass in the sorption of Ni by biomass-birnessite assemblages. Environmental Science & Technology 45:7338-7344. |
| Rhine E.D., Garcia-Dominguez E., Phelps C.D., Young L.Y. 2005. Environmental microbes can speciate and cycle arsenic. Environ. Sci. Technol. 39:9569-9573. |
| Ridley M.K., Hiemstra T., van Riemsdijk W.H., Machesky M.L. 2009. Inner-sphere complexation of cations at the rutile-water interface: A concise surface structural interpretation with the CD and MUSIC model. Geochim. Cosmochim. Acta 73:1841-1856. |
Sarret, G. et.al. 1999. Structural determination of Pb binding sites in Penicillium chrysogenum cell walls by EXAFS spectroscopy and solution chemistry. J. Synchrotron Rad. 6:414-416. |
| Suzuki, Y., S.D. Kelly, K.M. Kemner, and J.F. Banfield. 2002. Radionuclide contamination: Nanometre-size products of uranium bioreduction. Nature 419:134-134. |
| Sverjensky D.A., Fukushi K. 2006. A predictive model (ETLM) for As(III) adsorption and surface speciation on oxides consistent with spectroscopic data. Geochim. Cosmochim. Acta 70:3778-3802. |
*Templeton, A.S., T.P. Trainor, A.M. Spormann, M. Newville, S.R. Sutton, A. Dohnalkova, Y. Gorby, and G.E. Brown. 2003. Sorption versus biomineralization of Pb(II) within Burkholderia cepacia biofilms. Environ. Sci. Technol. 37:300-307. |
| Toner B., Manceau A., Webb S.M., Sposito G. 2006. Zinc sorption to biogenic hexagonal-birnessite particles within a hydrated bacterial biofilm. Geochim. Cosmochim. Acta 70:27-43. |
| vanRiemsdijk W.H., Koopal L.K., Kinniburgh D.G., Benedetti M.F., Weng L. 2006. Modeling the interactions between humics, ions, and mineral surfaces. Environ. Sci. Technol. 40:7473-7480. |
| Villalobos M., Lanson B., Manceau A., Toner B., Sposito G. 2006. Structural model for the biogenic Mn oxide produced by Pseudomonas putida. American Mineralogist 91:489-502. |
| Wang Q. ,E. Iriowen, S. Yuan, D.L. Sparks. 2011. Impact of sediment from St. Jones River, Delaware, USA on microbial functional stability in two local soils. J Bioremed Biodegrad S1:005. |
| Wu Y.X., Deng B.L., Xu H.F., Kornishi H. 2005. Chromium(III) oxidation coupled with microbially mediated Mn(II) oxidation. Geomicrobiology Journal 22:161-170. |
| Molecular and Surface Complexation Modeling |
| Adamescu A., Hamilton I.P., Al-Abadleh H.A. 2011. Thermodynamics of dimethylarsinic acid and arsenate interactions with hydrated iron-(oxyhydr)oxide clusters: DFT calculations. Environmental Science & Technology 45:10438-10444. |
Domagal-Goldman, S.D., K.W. Paul, D.L. Sparks and J.D. Kubicki. 2009. Quantum chemical study of the Fe(III)-desferrioxamine B siderophore complex—Electronic structure, vibrational frequencies, and equilibrium Fe-isotope fractionation. Geochim. Cosmochim. Acta 73(1):1-12. |
Fukushi K., Sverjensky D.A. 2007. A predictive model (ETLM) for arsenate adsorption and surface speciation on oxides consistent with spectroscopic and theoretical molecular evidence. Geochim. Cosmochim. Acta 71:3717-3745. |
| Juhasz A.L., Weber J., Smith E. 2011. Predicting arsenic relative bioavailability in contaminated soils using meta analysis and relative bioavailability/bioaccessibility regression models. Environmental Science & Technology 45:10676-10683. |
Kubicki, J.D., K.P. Paul, and D. L. Sparks. 2008. Periodic density functional theory calculations of bulk and the (010) surface of goethite. Geochemical Transactions 9:4. |
*Paul K.W., Borda M.J., Kubicki J.D., Sparks D.L. 2005. Effect of dehydration on sulfate coordination and speciation at the Fe-(Hydr)oxide-water interface: A molecular orbital/density functional theory and Fourier transform infrared spectroscopic investigation. Langmuir 21:11071-11078. |
Paul, K.W., J.D. Kubicki and D. L. Sparks. 2006. Quantum chemical calculations of sulfate adsorption at the Al- and Fe-(Hydr)oxide-H2O interface-Estimation of Gibbs free energies. Environ. Sci. Technol. 40:7717 -7724. |
Paul, K.W., J.D. Kubicki and D. L. Sparks. 2007. Sulphate adsorption at the Fe (hydr)oxide–H2O interface: comparison of cluster and periodic slab DFT predictions, European J Soil Sci. 58:978-988. |
| Phillips K.L., Di Toro D.M., Sandler S.I. 2010. Prediction of soil sorption coefficients using model molecular structures for organic matter and the quantum mechanical COSMO-SAC model. Environmental Science & Technology 45:1021-1027. |
Ridley M.K., Hiemstra T., van Riemsdijk W.H., Machesky M.L. 2009. Inner-sphere complexation of cations at the rutile-water interface: A concise surface structural interpretation with the CD and MUSIC model. Geochim. Cosmochim. Acta 73:1841-1856. |
Sverjensky D.A., Fukushi K. 2006. A predictive model (ETLM) for As(III) adsorption and surface speciation on oxides consistent with spectroscopic data. Geochim. Cosmochim. Acta 70:3778-3802. |
vanRiemsdijk W.H., Koopal L.K., Kinniburgh D.G., Benedetti M.F., Weng L. 2006. Modeling the interactions between humics, ions, and mineral surfaces. Environ. Sci. Technol. 40:7473-7480. |
Reviews |
| Borda, M.J., and D.L. Sparks. In Press. Kinetics and Mechanisms of Sorption/Desorption in Soils: A Multi-Scale Assessment, In A. Violante, et al., eds. Biophysico-Chemical Processes Of Metals And Metalloids In Soil Environments. IUPAC. |
*Brown, G.E., and G.A. Parks. 2001. Sorption of trace elements on mineral surfaces: Modern perspectives from spectroscopic studies, and comments on sorption in the marine environment. Intern. Geol. Rev. 43:963-1073. |
*Brown, G.E. Jr. and N.C. Sturchio. 2002. Overview of synchrotron radiation applications to low temperature geochemistry and environmental science. p. 1-115. In Fenter et. al. (eds.) Applications of Synchrotron Radiation in Low-Temperature Geochemistry and Environmental Sciences, Rev Mineral Geochem 49, Washington D.C. |
| Brown, G.E.Jr., et al. 2004. Molecular Environmental Science: An Assessment of Research Accomplishments, Available Synchrotron Radiation Facilities, and Needs. SLAC-Report-704. Stanford Linear Accelerator Center, Stanford Synchrotron Radiation Laboratory, Stanford University, Stanford, CA. |
| Chan, C.S., G. De Stasio, S.A. Welch, M. Girasole, B.H. Frazer, M.V. Nesterova, S. Fakra, and J.F. Banfield. 2004. Microbial polysaccharides template assembly of nanocrystal fibers. Science 303:1656-1658. |
| Chorover J., Kretzschmar R., Garcia-Pichel F., Sparks D.L. 2007. Soil biogeochemical processes within the Critical Zone. Elements 3:321-326. |
| Chorover J., Brusseau M.L. 2008. Kinetics of Sorption—Desorption, Kinetics of Water-Rock Interaction. pp. 109-149. |
| Fendorf, S.E., D.L. Sparks, G.M. Lamble, and M.J. Kelley. 1994. Applications of x-ray absorption fine structure spectroscopy to soils. Soil Sci. Soc. Am. J. 58:1583-1595. |
| Fortin, D. 2004. What biogenic minerals tell us. Science 303:1618-1619. |
| *Ginder-Vogel, M. and D. L. Sparks. 2010. The impacts of X-ray absorption spectroscopy on understanding soil processes and reaction mechanisms, p. 1-26. In Developments in Soil Science 34: Synchrotron-based Techniques in Soils and Sediments. B. Singh and M. Grafe, eds. Elsevier, Burlington, MA. |
Hirschmugl, C.J. 2002. Applications of storage ring infrared spectromicroscopy and reflection-absorption spectroscopy to geochemistry and environmental science. p. 317-340. In Fenter et. al. (eds.) Applications of Synchrotron Radiation in Low-Temperature Geochemistry and Environmental Sciences, Rev Mineral Geochem 49, Washington D.C. |
Hochella, M. F., Jr., J. F. Rakovan, K. M. Rosso, B. R. Bickmore and E. Rufe. 1999. New directions in mineral surface geochemical research using scanning probe microscopes. p. 37-56. In D. L. Sparks and T. J. Grundl (eds) Mineral-Water Interfacial Reactions, Kinetics and Mechanisms , ACS Symposium Series No. 715, Washington, DC. |
Katz, L. E. and E. J. Boyle-Wight. 2001. Application of spectroscopic methods to sorption model parameter estimation. p. 189-212. In H. M. Selim and D. L. Sparks (eds) Physical and chemical processes of water and solute transport/retention in soils, SSSA Spec. Pub. 56, SSSA, Madison, WI. |
Kirkpatrick, R. J., Y. Kim, C. A. Weiss, R. T. Cygan. 1997. NMR spectoscopic investigations of surface and interlayer species on minerals, clays and other oxides. p. 157-168. In Gonis et al. (eds.) Properties of Complex Inorganic Solids, Plenum Press, New York. |
| Lefevre, G. 2004. In situ Fourier-transform infrared spectroscopy studies of inorganic ions adsorption on metal oxides and hydroxides. Adv Colloid Interfac 107:109-123. |
*Manceau, A., M.A. Marcus and N. Tamura. 2002. Quantitative speciation of heavy metals in soils and sediments by synchrotron X-ray techniques p. 341-428. In Fenter et. al. (eds.) Applications of Synchrotron Radiation in Low-Temperature Geochemistry and Environmental Sciences, Rev Mineral Geochem 49, Washington D.C. |
| Matocha, C.J., K.G. Scheckel, and D.L. Sparks. 2005. Kinetics and mechanisms of soil biogeochemical processes, p. 309-342, In M. A. Tabatbai and D. L. Sparks, eds. Chemical Processes in Soils. Soil Science Society of America, Madison, WI. |
| McNear, D.H., Jr., R. Tappero, and D.L. Sparks. 2005. Shining light on metals in the environment. Elements 1:211-216. |
| Newman, D.K., and J.F. Banfield. 2002. Geomicrobiotogy: How molecular-scale interactions underpin biogeochemical systems. Science 296:1071-1077. |
Roberts, D.R., A.C. Scheinost and D.L. Sparks. 2003. Zinc speciation in contaminated soils combing direct and indirect characterization methods. p. 187-227. In H.M. Selim and W.L. Kingery (eds.) Geochemical and Hydrological Reactivity of Heavy Metals in Soils, Lewis Publishers, Boca Raton. |
Scheidegger, A. M. and D. L. Sparks. 1996. A critical assessment of sorption-desorption mechanisms at the soil mineral/water interface. Soil Sci. 161:813-831 |
| *Sparks, D.L. 2005. Sorption | Metals, p. 532-537, In D. Hillel, et al., eds. Encyclopedia of Soils in the Environment. Elsevier Ltd., Oxford UK. |
| *Sparks, D.L. 2005. Sorption-Desorption, Kinetics, p. 556-561, In D. Hillel, et al., eds. Encyclopedia of Soils in the Environment. Elsevier Ltd., Oxford UK. |
Sutton, S.R. et.al. 2002. Microfluoresence and microtomography analyses of heterogeneous earth and environmental materials p. 429-484 In Fenter et. al. (eds.) Applications of Synchrotron Radiation in Low-Temperature Geochemistry and Environmental Sciences, Rev Mineral Geochem 49, Washington D.C. |
| Tebo, B.M., J.R. Bargar, B.G. Clement, G.J. Dick, K.J. Murray, D. Parker, R. Verity, and S.M. Webb. 2004. Biogenic manganese oxides: Properties and mechanisms of formation. Annu Rev Earth Pl Sc 32:287-328. |
| Toor, G.S., S. Hunger, J.D. Peak, J.T. Sims and D.L. Sparks. 2006. Advances in the Characterization of Phosphorus in Organic Wastes: Environmental and Agronomic Applications, In Advances in Agronomy, 89:1-72 |
| * Required Papers |
