Douglass F. Taber . . . U. of Delaware

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Free Energy Relationships

from Eliel, Ernest Conformational Analysis, Washington, D.C. 1981, p. 11

Energy diff (kcal/mol).....Relative Rate..............% Stable Isomer

0 .......................................1.0......................................50

.24.....................................1.5......................................60

.50.....................................2.33....................................70

.82.....................................4.0......................................80

1.03...................................5.7......................................85

1.3.....................................9.0......................................90

1.7...................................19.0......................................95

2.7...................................99.0......................................99

4.1.................................999.0......................................99.9

these ratios are at room temperature (25 oC)



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