CHEM-651: Advanced Inorganic Chemistry I
Fall 2014
   
Instructor: Prof. Joel Rosenthal
Lectures: Tues + Thurs 5:00 - 6:15 PM (BRL 206)
Textbook: Concepts and Models of Inorganic Chemistry - Third Edition
  by Douglas, McDaniel & Alexander
Office Hours: By appointment
  Syllabus
  Description of Class Presentation
  Student Reviews
   
 

Please take a moment to evaluate this course using the link below:

http://www.udel.edu/courseevaladmin/

 

 

Course Outline
Date Lecture Topic Supplemental Material
8/26 Lecture 1 Structure of the Atom Atomic Wavefunctions
8/28 Lecture 2 Electronic Configurations Orbital Energetics
9/2 Lecture 3 Rationalizing Periodic Trends Periodic Trends
9/4 Lecture 4 Simple Bonding Models Platinum XANES
9/9 Lecture 5 Molecular Shape and Geometry  
9/11 Lecture 6 Molecular Symmetry Point Group Analysis
9/16 Lecture 7 Valence Bond Theory Methane PES
9/18 Lecture 8 Molecular Orbital Theory I Orbital Mixing and PES
9/23 Lecture 9 Molecular Orbital Theory II  
9/30   Midterm I  
10/2 Lecture 10 Acids and Bases Proton Affinity and IE
10/7 Lecture 11 Intro to Coordination Chemistry
10/9 Lecture 12 Crystal Field Theory Crystal Field Theory
10/14 Lecture 13 Ligand Field Theory I  
10/16 Lecture 14 Ligand Field Theory II and Carbonyl Chemistry
10/21 Lecture 15 Microstates and Term Symbols  
10/23 Lecture 16 Correlation and Tanabe-Sugano Diagrams  
10/30 Lecture 17 Tanabe-Sugano Diagrams and CT Spectra  
10/4   Election Day - No Classes  
11/6   Midterm II  
11/11,13 Lecture 18,19 Dissociative Reaction Mechanisms Substitution Kinetics
11/13,18 Lecture 19,20 Associative Reaction Mechanisms TS Diagrams
11/20,25 Lecture 21,22 Outer Sphere ET and Marcus Theory  
11/27   Thanksgiving - No Classes  
12/2 Lecture 23 Inner Sphere ET and Mixed Valency  
11/15   Class Presentations (9AM 219 BRL)  
Note: Course Outline is approximate and Subject to Change

 

Problem Sets
Date Problem Set Solution Set Statistics
  Problem Set #1 Solutions to PS #1  
 
 
  Problem Set #2 Solutions to PS #2  
 
 
  Problem Set #3 Solutions to PS #3  
 
 
  Problem Set #4 Solutions to PS #4  
 
 

 

Exams
Date Exam Solution Set Statistics
9/30 Midterm I Solutions to Midterm I Average = 76
High = 97.5, Low = 41.5
 
11/6 Midterm II Solutions to Midterm II Average = 63
High = 89; Low = 38
 

TBD

Final Solutions to Final