| CHEM-651: Advanced Inorganic Chemistry I |
| Fall 2011 |
| Instructor: | Prof. Joel Rosenthal |
| Lectures: | Tues + Thurs 12:30 - 1:45 PM (BRL 207) |
| Textbook: | Inorganic Chemistry - Third Edition (Recommended) |
| by Housecroft + Sharp | |
| Office Hours: | By appointment |
| Syllabus | |
| Final Project Description | |
| Student Reviews | |
| Please take a moment to evaluate this course using the link below: |
| Course Outline | |||
| Date | Lecture | Topic | Supplemental Material |
| 8/28 | Lecture 1 | Structure of the Atom | Atomic Wavefunctions |
| 8/30 | Lecture 2 | Electronic Configurations | Orbital Energetics |
| 9/4 | Lecture 3 | Rationalizing Periodic Trends | Periodic Trends |
| 9/6 | Lecture 4 | Simple Bonding Models | Platinum XANES |
| 9/11 | Lecture 5 | Molecular Shape and Geometry | |
| 9/13 | Lecture 6 | Molecular Symmetry | Point Group Analysis |
| 9/18 | Lecture 7 | Valence Bond Theory | Methane PES |
| 9/20 | Lecture 8 | Molecular Orbital Theory I | Orbital Mixing and PES |
| 9/25 | Lecture 9 | Molecular Orbital Theory II | |
| 9/27 | Lecture 10 | Acids and Bases | Proton Affinity and IE |
| 10/2 | Lecture 11 | Introduction to Coordination Chemistry | |
| 10/4 | Midterm | ||
| 10/9 | Lecture 12 | Crystal Field Theory | Crystal Field Theory |
| 10/11 | Lecture 13 | Ligand Field Theory | |
| 10/16 | Lecture 14 | Electronic Structure of Metal Carbonyls | |
| 10/18 | Lecture 15 | Electronic Spectroscopy and Microstates | Cu(II) UV-vis Abs |
| 10/23 | Lecture 16 | Microstates and Term Symbols | |
| 10/25 | Lecture 17 | Correlation and Tanabe-Sugano Diagrams | TS Diagrams |
| 10/30 | Lecture 18 | Basic Substitution Reactions and Kinetics | |
| 11/1 | Lecture 19 | Dissociative Reaction Mechanisms | Substitution Kinetics |
| 11/6 | Lecture 20 | Associative Reaction Mechanisms | |
| 11/8 | Lecture 21 | Fundamentals of Redox Chemistry | Half Reactions |
| 11/13 | Lecture 22 | Electrochemistry and Potential Diagrams | Frost + Pourbaix Diagrams |
| 11/15 | Lecture 23 | Outer Sphere ET and Marcus Theory | |
| 11/20 | Midterm II | ||
| 11/22 | Thanksgiving | ||
| 11/27 | Lecture 24 | Inner Sphere ET and Mixed Valency | |
| 11/29 | Lecture 25 | Introduction to Organometallic Chemistry | |
| 12/4 | Lecture 26 | Organometallic Reactions Involving Modification of Ligands | |
| 12/8 | Class Presentations (9AM 219 BRL) | ||
Note: Course Outline is approximate and Subject to Change |
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| Problem Sets | |||
| Due Date | Problem Set | Solution Set | Statistics |
| 9/11 | Problem Set #1 | Solutions to PS #1 | Avg = 53/60 |
| High = 60; Low = 34 | |||
| Standard Deviation = 7.5 | |||
| 9/27 | Problem Set #2 | Solutions to PS #2 | Avg = 74/90 |
| High = 85; Low = 50 | |||
| Standard Deviation = 8.4 | |||
| 10/30 | Problem Set #3 | Solutions to PS #3 | Avg = 79 |
| High = 97; Low = 36 | |||
| Standard Deviation = 15.6 | |||
| Exams | |||
| Date | Exam | Solution Set | Statistics |
| 10/4 | Midterm I | Solutions to Midterm I | Avg = 76.4 |
| High = 96; Low = 46 | |||
| Standard Deviation = 14.8 | |||
| 11/20 | Midterm II | Solutions to Midterm II | Avg = 59 |
| High = 81; Low = 28 | |||
| Standard Deviation = 13.6 | |||
12/11 3:30 - 6:30 PM BRL 207 |
Final | Solutions to Final | |